For me, it’s hands down Flameshot. The best screenshot tool in the world - I’ve got it hooked up to my PrtScrn key for super easy screenshots.
I also love Kwrite as a Notepad++ alternative, and KolourPaint as a MSPaint alternative
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Well, the permanently open applications on my system are: claws-mail, Pale Moon (browser forked from Firefox), konqueror (TDE file manager), konsole (TDE terminal), and Aqualung (music player). Other good friends include kate, Inkscape, and OpenSCAD (despite its flakiness). And I get a lot of mileage out of DOSBox.
If the OP hadn’t specified desktop software, I’d also name Portage.